Dithiocarbamic Acid Synthesis Essay

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  • Copper-Catalyzed Aerobic Oxidative Reaction of C60 with Aliphatic Primary Amines and CS2


    The Journal of Organic Chemistry201883 (4), 2125-2130

    Abstract | Full Text HTML | PDF | PDF w/ Links

  • Synthesis of N,S-Heterocycles and Dithiocarbamates by the Reaction of Dithiocarbamic Acids and S-Alkyl Dithiocarbamates with Nitroepoxides

    AzimZiyaei HalimehjaniYazdanbakhshLotfi Nosood

    Organic Letters201719 (24), 6748-6751

    Abstract | Full Text HTML | PDF | PDF w/ Links

  • A synthesis of thioxo[3.3.3]propellanes from acenaphthoquinone-malononitrile adduct, primary amines and CS 2 in water

    IssaYavariAliyehKhajeh-KhezriMohammad RezaHalvagar

    Arabian Journal of Chemistry201811 (2), 188-195

  • Synthesis of novel dithiocarbamates and xanthates using dialkyl azodicarboxylates: S N bond formation

    AzimZiyaei HalimehjaniBlankaKlepetářováPetrBeier


  • Use of Glycosyl Dithiocarbamates: Small Molecule ‘Turn-on’ Fluorescent Probe for Carbohydrate Binding Proteins


    ChemistrySelect20183 (2), 648-652

  • Synthesis of a novel category of Ugi adducts using succinic acid, succinic anhydride and maleic anhydride and their application in post-Ugi reactions for synthesis of functionalized piperazine 2,5-diones

    AzimZiyaei HalimehjaniMarziehSharifi

    Tetrahedron201773 (39), 5778-5783

  • Synthesis of Thiazolidine-2-thiones through a One-Pot A 3 -Coupling-Carbon Disulfide Incorporation Process

    Anton A.NechaevAnatoly A.PeshkovKristofVan HeckeVsevolod A.PeshkovErik V.Van der Eycken

    European Journal of Organic Chemistry20172017 (6), 1063-1069

  • Dithiocarbamate as an efficient intermediate for the synthesis of 2-(alkylthio)thiazol-4(5 H )-ones

    AzimZiyaei HalimehjaniM. AliAlaeiFarzanehSoleymani MovahedNeginJomehMohammad R.Saidi

    Journal of Sulfur Chemistry201637 (5), 529-536

  • A one-pot three-component synthesis of dithiocarbamates starting from vinyl pyridines and vinyl pyrazine under solvent- and catalyst-free conditions

    Azim ZiyaeiHalimehjaniJürgenMartensTorbenSchlüter

    Tetrahedron201672 (27-28), 3958-3965

  • Multicomponent synthesis of dithiocarbamates starting from vinyl sulfones/sulfoxides and their use in polymerization reactions

    Azim ZiyaeiHalimehjaniRezaMohtashamAbbasShockraviJürgenMartens

    RSC Advances20166 (79), 75223-75226

  • Investigation of the reaction of dithiocarbamic acid salts with trimethyl orthoformate and styrene epoxide

    AzimZiyaei HalimehjaniMojtabaHajilou ShayeganShiva ShakoriPoshtehVahidAmaniBehrouzNotashMohammad M.Hashemi

    Tetrahedron Letters201556 (51), 7124-7127

  • An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2-Substituted Benzimidazoles

    John A.GladyszHamidReza SafaeiSaraNouri

    Helvetica Chimica Acta201497 (10.1002/hlca.v97.11), 1539-1545

  • Synthesis of α-phthalimido-α′-dithiocarbamato propan-2-ols via a one-pot, three-component epoxide ring-opening in water

    Azim ZiyaeiHalimehjaniSeyyed EmadHooshmandElham ValiShamiri

    Tetrahedron Letters201455, 5454-5457

  • A rapid and convenient synthesis of gem-bis(dithiocarbamate) derivatives from primary aliphatic amines, carbon disulfide, and aromatic aldehydes using boron trifluoride-diethyl etherate

    FirouzehNematiAliGhorbani Gharjeh GhiyaeiBehrouzNotashMojtaba HajilooShayeganVahidAmani

    Tetrahedron Letters2014,

  • Four-Membered Ring Systems



  • A novel series of dithiocarbamic acid 6,11-dioxo-6,11-dihydro-1H-anthra[1,2-d]imidazol-2-yl methyl esters were synthesized and their cytotoxic and apoptotic activities were evaluated on HeLa cells. Some of these compounds showed potent cytotoxic activities and are able to induce the apoptosis mechanism in this cell line. Especially, 2c, 2d, and 2f had a high cytotoxic activity with an IC50 value of 8 or 10 μM at 24 h. These three compounds also induced HeLa cell apoptosis as compared to mitoxantrone. Particularly, 3 μM of 2f induced a high rate of early apoptotic cells (12.9%) at 6 h whereas mitoxantrone induced early apoptosis (5.5%) at 24 h. Compound 2c demonstrated a high ADP/ATP ratio (9.31) in HeLa cells at 12 h compared to mitoxantrone or other compounds, suggesting that 2c might induce HeLa cell apoptosis through the mitochondrial pathway. Caspase-3 activity started to increase after treatment with 6 μM of 2c for 6 h, and the maximal peak of activity was obtained at 12 h of incubation time. All three compounds were found to be potent apoptotic inducers compared to mitoxantrone.

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